Major culinary copper companies: Mauviel, Bourgeat, Dehilerin (French) Falk Culinair (Belgian) use 2.5mm copper, and all of these have stainless bimetal bonded inside for an easy to care for surface. (The three French companies also make a tin lined line; Mauviel's is quite beautifully hand hammered!!) The three French companies use polished copper which any one of 10 or so copper polishes takes care of when you wash your pots. Real copper polishes easily. Copper wash or plate as in Revere Ware is harder to maintain and polish. Falk uses brushed copper and it cleans up easliy with Bar Keepers Friend and a Scotch Brite pad.
Now, polishing should not be the reason to not buy good copper cookware. However, the price will be an issue; it is expensive as it is the real thing. Also, it is heavy and that will not suit everyone either.
Other companies: Lara copper form Tasmania, available on the internet, Handmade by a metalsmith. Tin lined, medium weight, very good for the home, great on residential ranges gas or electric or glass top.
Tin is soft and the temp needs to be under 450* F ... not a problem for most uses as most American pans in use say oven safe to 400* or 450* at most, some even less. Tin cannot be scoured...soak the pan in hot sudsy water and wash with a sponge...never had a problem, tin darkens as it ages-can't do squat about it, and will need to be renewed after 5 or so years of use in the home. There are many retinners available...again use the internet. If you really love cooking, nothing sounds like food sauteeing in a tin lined copper pan...music to your ears, really. Ruffoni and Puppeni from Italy are less rustic in appearence, but beautifully crafted medium weight copper cookware.
I know this beacuse I have invested in good copper cookware and use it daily. It is beautiful and most excellent to cook with. And if you can afford top line AllClad, you can afford good copper.
Beware what looks like a heavy copper pan but is light weight. Some of this from Alsace was circulating stores and is not good for cooking. Beware copper plated or electroplated tin linings...no durability, no use.
What of AllClad or Calphalon copper lines...or other companies claiming copper in their pans...CIA Master's collection, Daniel Bollud collection etc. The copper component is thin, but real. Basically these are quality aluminum pans, and the copper if anything further evens out the responsivness. Are they really worth the extra $$$. I put my money with the heavy 2.5mm commercial French and Belgium pans which are about the same cost. I'll be willing them to my ancestors!
ok ... where to shop for it... online...
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and often: smart bargains, Marshalls, various Kitchen stores like CHefs Catalogue, Cooking.com, Williams Sanoma, Kitchen Kapers, etc.